Database of Zeolite Structures
 
Framework Type OSI
31P MAS NMR spectrum of calcined UiO-6


Note: Toggle plots by clicking on the legend

Peak
T site
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Assigment
(topological)
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
P1/P2
T2/T3
Q4(4Al)
-30.76
1.000
2.72
0.237
P2/P1
T3/T2
Q4(4Al)
-28.13
1.000
2.72
0.237
P3
T1
Q4(4Al)
-25.66
2.000
2.72
0.237


References
Spectrum

  Authors: Halvorsen, E.N.
  Title: Synthesis and Characterisation of Aluminophosphate Molecular Sieves
  Reference: D.Sc. Thesis, University of Oslo, , (1996)
  Figure: Section 5.4 Figure 2b  

Peak Assignment

  Authors: Halvorsen, E.N.
  Title: Synthesis and Characterisation of Aluminophosphate Molecular Sieves
  Reference: D.Sc. Thesis, University of Oslo, , (1996)
  Method: relative intensities, average bond angles
  Figure: Section 5.4 Figure 2b  

Crystal Structure

  Authors: Akporiaye, D.E., Fjellvåg, H., Halvorsen, E.N., Haug, T., Karlsson, A. and Lillerud, K.P.
  Title: UiO-6: a novel 12-ring A1PO4, made in an inorganic-organic cation system
  Reference: Chem. Commun., , 1553-1554 (1996)

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
Spectrum information

  Obs. freq. not given
  Pulse sequence single pulse
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentPartial peak assignments are based on relative peak areas

Chemical Formula

  [Al - P - O]-OSI

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)

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