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ITQ-52 (calcined)
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Reference Material
Framework Type
IFW
Reference Material
Material Name:
ITQ-52
Chemical Formula:
[
B
3.8
Si
60.2
O
128
]
-
IFW
Unit Cell:
monoclinic
C 1 2/m 1 (# 12)
a'
= 21.4008 Å
b'
= 17.9064 Å
c'
= 12.3678 Å
α' = 90.000°
β' = 125.092°
γ' = 90.000°
Framework Density:
16.5 T/1000 Å
3
Channels:
[001]
10
5.3 x 5.8* <-> [010]
8
3.2 x 5.3* <-> [110]
8
3.2 x 5.3*
Dimensionality
Sorption (molecular cross section > 3.4Å):
1-dimensional
Topological (pore opening > 6-ring):
3-dimensional
References:
Jorda, J.L.
"Improved Rietveld refinement"
private communication
,
, (2013)
Simancas, R., Jorda, J.L., Rey, F., Corma, A., Cantin, A., Peral, I. and Popescu, C.
"A New Microporous Zeiolitic Silicoborate (ITQ-52) with interconnected Small and Medium Pores"
J. Am. Chem. Soc.
,
136
, 3342-3345 (2014)
Material name:
ITQ-52
Chemical formula:
[
B
3.8
Si
60.2
O
128
]
-
IFW
Name and Code derivation:
I
nstituto de
T
ecnologia
Q
uimica Valencia - fifty-two
I
TQ-52 (
f
ifty-t
w
o)
IFW
Limiting Rings
10-ring viewed along [101]
8-ring viewed along [111]
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IZA-SC
)