##TITLE=              31P MAS NMR spectrum of as-made AlPO-ZON (with fluoride and tetramethylammonium template)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Roux et al. Microporous Mesoporous Mater., 63, 163-176 (2003) Figure 3b
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/22 15:04:11
##SOURCE REFERENCE=   ZON-31P-Roux-2003-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              ZON
##NAMES=              AlPO-ZON
##NAMES=              UiO-7
##SAMPLE DESCRIPTION= AlPO-ZON, as-made

$$Bibliographic information 
##$AUTHORS=           Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
##$TITLE=             Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
##$JOURNAL=           Microporous and Mesoporous Materials
##$VOLUME=            63
##$PAGES=             163-176
##$YEAR=              2003
##$DOI=               10.1016/S1387-1811(03)00460-8
##$FIGURE=            Figure 3b

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         4
##$PEAK LABELS=        P2         P1         P3         P4        
##$PEAK TSITES=        T1         T2         T3         T4        
##$PEAK POSITIONS=    -32.1054   -20.9035   -19.532    -16.7445   
##$PEAK AREAS=         1.         1.         1.         1.        
##$PEAK WIDTHS=        1.65729    1.31327    1.38411    1.29077   
##$PEAK SHAPES=        0.79098    0.79098    0.79098    0.79098   
##$NUMBERING REF=     Akporiaye et al. J. Phys. Chem., 100, 16641-16646 (1996)
##$ASSIGN REF=        Roux et al. Microporous Mesoporous Mater., 63, 163-176 (2003) Figure 3a and 4a
##$ASSIGN METHOD=     2D correlation NMR, cross polarization
##$COMMENT=           Spectrum was acquired with simultaneous 1H and 27Al decoupling. Peak assignments are based on a 2D 31P/31P correlation spectrum and a 19F/31P cross polarization spectrum.

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 161.9
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     3500-8000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -10.                  
##LASTX=              -39.85                
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            598
##FIRSTY=              0.01113              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -10.                 0.01113              
 -10.05               0.01075              
 -10.1                0.01080              
 -10.15               0.01024              
 -10.2                0.00995              
 -10.25               0.00994              
 -10.3                0.00926              
 -10.35               0.00944              
 -10.4                0.01006              
 -10.45               0.01000              
 -10.5                0.00988              
 -10.55               0.01015              
 -10.6                0.01081              
 -10.65               0.01146              
 -10.7                0.01159              
 -10.75               0.01165              
 -10.8                0.01226              
 -10.85               0.01295              
 -10.9                0.01325              
 -10.95               0.01319              
 -11.                 0.01318              
 -11.05               0.01320              
 -11.1                0.01319              
 -11.15               0.01319              
 -11.2                0.01319              
 -11.25               0.01321              
 -11.3                0.01319              
 -11.35               0.01310              
 -11.4                0.01355              
 -11.45               0.01403              
 -11.5                0.01396              
 -11.55               0.01446              
 -11.6                0.01486              
 -11.65               0.01480              
 -11.7                0.01530              
 -11.75               0.01605              
 -11.8                0.01643              
 -11.85               0.01638              
 -11.9                0.01686              
 -11.95               0.01731              
 -12.                 0.01723              
 -12.05               0.01718              
 -12.1                0.01731              
 -12.15               0.01715              
 -12.2                0.01651              
 -12.25               0.01643              
 -12.3                0.01625              
 -12.35               0.01563              
 -12.4                0.01561              
 -12.45               0.01540              
 -12.5                0.01469              
 -12.55               0.01408              
 -12.6                0.01396              
 -12.65               0.01397              
 -12.7                0.01398              
 -12.75               0.01454              
 -12.8                0.01493              
 -12.85               0.01476              
 -12.9                0.01465              
 -12.95               0.01567              
 -13.                 0.01653              
 -13.05               0.01641              
 -13.1                0.01687              
 -13.15               0.01753              
 -13.2                0.01810              
 -13.25               0.01874              
 -13.3                0.01881              
 -13.35               0.01898              
 -13.4                0.01961              
 -13.45               0.01962              
 -13.5                0.01990              
 -13.55               0.02047              
 -13.6                0.02041              
 -13.65               0.02085              
 -13.7                0.02128              
 -13.75               0.02121              
 -13.8                0.02215              
 -13.85               0.02346              
 -13.9                0.02456              
 -13.95               0.02571              
 -14.                 0.02689              
 -14.05               0.02799              
 -14.1                0.02913              
 -14.15               0.03076              
 -14.2                0.03254              
 -14.25               0.03426              
 -14.3                0.03602              
 -14.35               0.03746              
 -14.4                0.03836              
 -14.45               0.03890              
 -14.5                0.03957              
 -14.55               0.03981              
 -14.6                0.03982              
 -14.65               0.04045              
 -14.7                0.04058              
 -14.75               0.04076              
 -14.8                0.04199              
 -14.85               0.04320              
 -14.9                0.04436              
 -14.95               0.04631              
 -15.                 0.04968              
 -15.05               0.05331              
 -15.1                0.05791              
 -15.15               0.06436              
 -15.2                0.07067              
 -15.25               0.07731              
 -15.3                0.08498              
 -15.35               0.09307              
 -15.4                0.10088              
 -15.45               0.10933              
 -15.5                0.11871              
 -15.55               0.12633              
 -15.6                0.13819              
 -15.65               0.15385              
 -15.7                0.16356              
 -15.75               0.17701              
 -15.8                0.19418              
 -15.85               0.20822              
 -15.9                0.22449              
 -15.95               0.24219              
 -16.                 0.26009              
 -16.05               0.28088              
 -16.1                0.30322              
 -16.15               0.32669              
 -16.2                0.35197              
 -16.25               0.37795              
 -16.3                0.40348              
 -16.35               0.42945              
 -16.4                0.45798              
 -16.45               0.48362              
 -16.5                0.50467              
 -16.55               0.5242               
 -16.6                0.54311              
 -16.65               0.5573               
 -16.7                0.56510              
 -16.75               0.57091              
 -16.8                0.57110              
 -16.85               0.56453              
 -16.9                0.55393              
 -16.95               0.53946              
 -17.                 0.52187              
 -17.05               0.50079              
 -17.1                0.47454              
 -17.15               0.44926              
 -17.2                0.42394              
 -17.25               0.39351              
 -17.3                0.36782              
 -17.35               0.34467              
 -17.4                0.31908              
 -17.45               0.29565              
 -17.5                0.27537              
 -17.55               0.25676              
 -17.6                0.23902              
 -17.65               0.22555              
 -17.7                0.21521              
 -17.75               0.20546              
 -17.8                0.19717              
 -17.85               0.19159              
 -17.9                0.18793              
 -17.95               0.18431              
 -18.                 0.18217              
 -18.05               0.18171              
 -18.1                0.18234              
 -18.15               0.18428              
 -18.2                0.18711              
 -18.25               0.19081              
 -18.3                0.19583              
 -18.35               0.20174              
 -18.4                0.20843              
 -18.45               0.21650              
 -18.5                0.22680              
 -18.55               0.23848              
 -18.6                0.25065              
 -18.65               0.26356              
 -18.7                0.27841              
 -18.75               0.29530              
 -18.8                0.31371              
 -18.85               0.33356              
 -18.9                0.35382              
 -18.95               0.37472              
 -19.                 0.39791              
 -19.05               0.42265              
 -19.1                0.44578              
 -19.15               0.46668              
 -19.2                0.49156              
 -19.25               0.51551              
 -19.3                0.53481              
 -19.35               0.55338              
 -19.4                0.57068              
 -19.45               0.58481              
 -19.5                0.59509              
 -19.55               0.60340              
 -19.6                0.60941              
 -19.65               0.61154              
 -19.7                0.60885              
 -19.75               0.60335              
 -19.8                0.59663              
 -19.85               0.58824              
 -19.9                0.5761               
 -19.95               0.56404              
 -20.                 0.55394              
 -20.05               0.54215              
 -20.1                0.53274              
 -20.15               0.52688              
 -20.2                0.52264              
 -20.25               0.52168              
 -20.3                0.52384              
 -20.35               0.52885              
 -20.4                0.53749              
 -20.45               0.54769              
 -20.5                0.55916              
 -20.55               0.57296              
 -20.6                0.58696              
 -20.65               0.59898              
 -20.7                0.60910              
 -20.75               0.61946              
 -20.8                0.62669              
 -20.85               0.62839              
 -20.9                0.62523              
 -20.95               0.61869              
 -21.                 0.60899              
 -21.05               0.59473              
 -21.1                0.57410              
 -21.15               0.55043              
 -21.2                0.52514              
 -21.25               0.49708              
 -21.3                0.46791              
 -21.35               0.43552              
 -21.4                0.40014              
 -21.45               0.36900              
 -21.5                0.34091              
 -21.55               0.31255              
 -21.6                0.28342              
 -21.65               0.25773              
 -21.7                0.23565              
 -21.75               0.21625              
 -21.8                0.20107              
 -21.85               0.18529              
 -21.9                0.17062              
 -21.95               0.16411              
 -22.                 0.15793              
 -22.05               0.14990              
 -22.1                0.14192              
 -22.15               0.13271              
 -22.2                0.12419              
 -22.25               0.11691              
 -22.3                0.10923              
 -22.35               0.10309              
 -22.4                0.09705              
 -22.45               0.08940              
 -22.5                0.08322              
 -22.55               0.07769              
 -22.6                0.07194              
 -22.65               0.06711              
 -22.7                0.06351              
 -22.75               0.05988              
 -22.8                0.05573              
 -22.85               0.05356              
 -22.9                0.05189              
 -22.95               0.04947              
 -23.                 0.04756              
 -23.05               0.04660              
 -23.1                0.04616              
 -23.15               0.04559              
 -23.2                0.04492              
 -23.25               0.04458              
 -23.3                0.04464              
 -23.35               0.04466              
 -23.4                0.04462              
 -23.45               0.04466              
 -23.5                0.04471              
 -23.55               0.04415              
 -23.6                0.04383              
 -23.65               0.04385              
 -23.7                0.04282              
 -23.75               0.04153              
 -23.8                0.04043              
 -23.85               0.03928              
 -23.9                0.03814              
 -23.95               0.03696              
 -24.                 0.03582              
 -24.05               0.03485              
 -24.1                0.03293              
 -24.15               0.03069              
 -24.2                0.02957              
 -24.25               0.02845              
 -24.3                0.02744              
 -24.35               0.02693              
 -24.4                0.02642              
 -24.45               0.02568              
 -24.5                0.02530              
 -24.55               0.02588              
 -24.6                0.02654              
 -24.65               0.02707              
 -24.7                0.02765              
 -24.75               0.02824              
 -24.8                0.02878              
 -24.85               0.02940              
 -24.9                0.03007              
 -24.95               0.02985              
 -25.                 0.02911              
 -25.05               0.02856              
 -25.1                0.02806              
 -25.15               0.02725              
 -25.2                0.02596              
 -25.25               0.02426              
 -25.3                0.02242              
 -25.35               0.02088              
 -25.4                0.01978              
 -25.45               0.01865              
 -25.5                0.01748              
 -25.55               0.01634              
 -25.6                0.01522              
 -25.65               0.01392              
 -25.7                0.01309              
 -25.75               0.01317              
 -25.8                0.01322              
 -25.85               0.01318              
 -25.9                0.01319              
 -25.95               0.01321              
 -26.                 0.01312              
 -26.05               0.01330              
 -26.1                0.01393              
 -26.15               0.01408              
 -26.2                0.01394              
 -26.25               0.01401              
 -26.3                0.01454              
 -26.35               0.01526              
 -26.4                0.01563              
 -26.45               0.01557              
 -26.5                0.01608              
 -26.55               0.01651              
 -26.6                0.01642              
 -26.65               0.01640              
 -26.7                0.01642              
 -26.75               0.01642              
 -26.8                0.01642              
 -26.85               0.01640              
 -26.9                0.01646              
 -26.95               0.01642              
 -27.                 0.01589              
 -27.05               0.01525              
 -27.1                0.01470              
 -27.15               0.01414              
 -27.2                0.01348              
 -27.25               0.01312              
 -27.3                0.01319              
 -27.35               0.01323              
 -27.4                0.01311              
 -27.45               0.01327              
 -27.5                0.01391              
 -27.55               0.01398              
 -27.6                0.01417              
 -27.65               0.01479              
 -27.7                0.01478              
 -27.75               0.01508              
 -27.8                0.01566              
 -27.85               0.01565              
 -27.9                0.01557              
 -27.95               0.01566              
 -28.                 0.01563              
 -28.05               0.01507              
 -28.1                0.01465              
 -28.15               0.01487              
 -28.2                0.01550              
 -28.25               0.01564              
 -28.3                0.01569              
 -28.35               0.01634              
 -28.4                0.01745              
 -28.45               0.01864              
 -28.5                0.01977              
 -28.55               0.02093              
 -28.6                0.02205              
 -28.65               0.02325              
 -28.7                0.02440              
 -28.75               0.02503              
 -28.8                0.02561              
 -28.85               0.02612              
 -28.9                0.02611              
 -28.95               0.02613              
 -29.                 0.02600              
 -29.05               0.02538              
 -29.1                0.02465              
 -29.15               0.02453              
 -29.2                0.02443              
 -29.25               0.02321              
 -29.3                0.02263              
 -29.35               0.02301              
 -29.4                0.02360              
 -29.45               0.02412              
 -29.5                0.02491              
 -29.55               0.02618              
 -29.6                0.02782              
 -29.65               0.03002              
 -29.7                0.03224              
 -29.75               0.03392              
 -29.8                0.03554              
 -29.85               0.03753              
 -29.9                0.03990              
 -29.95               0.04226              
 -30.                 0.04421              
 -30.05               0.04582              
 -30.1                0.04753              
 -30.15               0.04972              
 -30.2                0.05210              
 -30.25               0.05437              
 -30.3                0.05661              
 -30.35               0.05921              
 -30.4                0.06226              
 -30.45               0.06571              
 -30.5                0.06965              
 -30.55               0.07368              
 -30.6                0.07772              
 -30.65               0.08223              
 -30.7                0.08716              
 -30.75               0.09251              
 -30.8                0.09828              
 -30.85               0.10419              
 -30.9                0.11140              
 -30.95               0.11875              
 -31.                 0.12399              
 -31.05               0.13598              
 -31.1                0.15189              
 -31.15               0.16446              
 -31.2                0.18206              
 -31.25               0.19962              
 -31.3                0.21275              
 -31.35               0.22727              
 -31.4                0.24333              
 -31.45               0.26149              
 -31.5                0.28188              
 -31.55               0.29961              
 -31.6                0.31569              
 -31.65               0.33248              
 -31.7                0.34931              
 -31.75               0.36526              
 -31.8                0.37961              
 -31.85               0.39184              
 -31.9                0.40146              
 -31.95               0.40914              
 -32.                 0.41524              
 -32.05               0.41888              
 -32.1                0.41966              
 -32.15               0.41760              
 -32.2                0.41311              
 -32.25               0.40691              
 -32.3                0.39769              
 -32.35               0.38591              
 -32.4                0.37509              
 -32.45               0.36068              
 -32.5                0.34379              
 -32.55               0.32971              
 -32.6                0.31318              
 -32.65               0.29497              
 -32.7                0.27851              
 -32.75               0.26303              
 -32.8                0.24482              
 -32.85               0.22629              
 -32.9                0.21272              
 -32.95               0.19737              
 -33.                 0.18185              
 -33.05               0.17078              
 -33.1                0.16230              
 -33.15               0.15488              
 -33.2                0.14636              
 -33.25               0.13532              
 -33.3                0.12546              
 -33.35               0.11629              
 -33.4                0.10640              
 -33.45               0.09841              
 -33.5                0.09149              
 -33.55               0.08462              
 -33.6                0.07819              
 -33.65               0.07253              
 -33.7                0.06775              
 -33.75               0.06376              
 -33.8                0.06032              
 -33.85               0.05672              
 -33.9                0.05343              
 -33.95               0.05168              
 -34.                 0.04978              
 -34.05               0.04731              
 -34.1                0.04502              
 -34.15               0.04309              
 -34.2                0.04173              
 -34.25               0.04059              
 -34.3                0.03892              
 -34.35               0.03708              
 -34.4                0.03547              
 -34.45               0.03432              
 -34.5                0.03369              
 -34.55               0.03303              
 -34.6                0.03175              
 -34.65               0.02991              
 -34.7                0.02885              
 -34.75               0.02841              
 -34.8                0.02778              
 -34.85               0.02773              
 -34.9                0.02752              
 -34.95               0.02691              
 -35.                 0.02693              
 -35.05               0.02661              
 -35.1                0.02604              
 -35.15               0.02605              
 -35.2                0.02619              
 -35.25               0.02593              
 -35.3                0.02531              
 -35.35               0.02479              
 -35.4                0.02391              
 -35.45               0.02268              
 -35.5                0.02154              
 -35.55               0.02038              
 -35.6                0.01929              
 -35.65               0.01812              
 -35.7                0.01641              
 -35.75               0.01485              
 -35.8                0.01390              
 -35.85               0.01334              
 -35.9                0.01274              
 -35.95               0.01229              
 -36.                 0.01236              
 -36.05               0.01288              
 -36.1                0.01351              
 -36.15               0.01405              
 -36.2                0.01459              
 -36.25               0.01552              
 -36.3                0.01686              
 -36.35               0.01798              
 -36.4                0.01802              
 -36.45               0.01831              
 -36.5                0.01884              
 -36.55               0.01828              
 -36.6                0.01757              
 -36.65               0.01709              
 -36.7                0.01651              
 -36.75               0.01546              
 -36.8                0.01419              
 -36.85               0.01313              
 -36.9                0.01253              
 -36.95               0.01205              
 -37.                 0.01137              
 -37.05               0.01078              
 -37.1                0.01116              
 -37.15               0.01189              
 -37.2                0.01241              
 -37.25               0.01293              
 -37.3                0.01389              
 -37.35               0.01510              
 -37.4                0.01624              
 -37.45               0.01744              
 -37.5                0.01839              
 -37.55               0.01885              
 -37.6                0.01891              
 -37.65               0.01858              
 -37.7                0.01780              
 -37.75               0.01662              
 -37.8                0.01546              
 -37.85               0.01430              
 -37.9                0.01317              
 -37.95               0.01211              
 -38.                 0.01046              
 -38.05               0.00893              
 -38.1                0.00843              
 -38.15               0.00787              
 -38.2                0.00744              
 -38.25               0.00755              
 -38.3                0.00803              
 -38.35               0.00900              
 -38.4                0.01019              
 -38.45               0.01131              
 -38.5                0.01285              
 -38.55               0.01477              
 -38.6                0.01640              
 -38.65               0.01704              
 -38.7                0.01759              
 -38.75               0.01807              
 -38.8                0.01803              
 -38.85               0.01814              
 -38.9                0.01775              
 -38.95               0.01646              
 -39.                 0.01519              
 -39.05               0.01450              
 -39.1                0.01384              
 -39.15               0.01262              
 -39.2                0.01197              
 -39.25               0.01118              
 -39.3                0.01000              
 -39.35               0.00988              
 -39.4                0.00995              
 -39.45               0.01001              
 -39.5                0.01061              
 -39.55               0.01115              
 -39.6                0.01190              
 -39.65               0.01311              
 -39.7                0.01428              
 -39.75               0.01541              
 -39.8                0.01656              
 -39.85               0.01771              
##END=
