##TITLE=              31P MAS NMR spectrum of as-made EMM-8 (with fluoride and N,N-dimethylamino-4-pyridine template)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Afeworki et al. Microporous Mesoporous Mater., 103, 216-224 (2007) Figure 4a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/22 12:27:13
##SOURCE REFERENCE=   SFO-31P-Afeworki-2007-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              SFO
##NAMES=              EMM-8
##NAMES=              SSZ-51
##SAMPLE DESCRIPTION= EMM-8, as-made

$$Bibliographic information 
##$AUTHORS=           Afeworki, M., Cao, G., Dorset, D.L., Strohmaier, K.G., Kennedy, G.J.
##$TITLE=             Multinuclear and multidimensional solid-state NMR characterization of EMM-8
##$JOURNAL=           Microporous and Mesoporous Materials
##$VOLUME=            103
##$PAGES=             216-224
##$YEAR=              2007
##$DOI=               10.1016/j.micromeso.2007.01.048
##$FIGURE=            Figure 4a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         4
##$PEAK LABELS=        P1         P3         P2         P4        
##$PEAK TSITES=        T2         T3         T1         T4        
##$PEAK POSITIONS=    -22.5342   -19.9543   -16.1216   -15.0583   
##$PEAK AREAS=         1.         1.         1.         1.        
##$PEAK WIDTHS=        1.75561    1.75561    1.75561    1.75561   
##$PEAK SHAPES=        0.55421    0.55421    0.55421    0.55421   
##$NUMBERING REF=     Morris et al. Chem. Mater., 16, 2844-2851 (2004)
##$ASSIGN REF=        Afeworki et al. Microporous Mesoporous Mater., 103, 216-224 (2007) Figure 8a
##$ASSIGN METHOD=     2D correlation NMR
##$COMMENT=           Peak assignments based on a 2D 27Al/31P correlation spectrum

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 202
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     10000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=              5.                   
##LASTX=              -44.4                 
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            495
##FIRSTY=             -0.00866              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
  5.                 -0.00866              
  4.9                -0.00866              
  4.8                -0.00866              
  4.7                -0.00865              
  4.6                -0.00861              
  4.5                -0.00782              
  4.4                -0.00573              
  4.3                -0.00258              
  4.2                -0.00049              
  4.1                 0.00199              
  4.                  0.00367              
  3.9                 0.00363              
  3.8                 0.00458              
  3.7                 0.00622              
  3.6                 0.00791              
  3.5                 0.00977              
  3.4                 0.00988              
  3.3                 0.01153              
  3.2                 0.01286              
  3.1                 0.01289              
  3.                  0.01289              
  2.9                 0.01285              
  2.8                 0.01461              
  2.7                 0.01668              
  2.6                 0.01795              
  2.5                 0.01886              
  2.4                 0.01895              
  2.3                 0.02048              
  2.2                 0.02228              
  2.1                 0.02470              
  2.                  0.02852              
  1.9                 0.03264              
  1.8                 0.03445              
  1.7                 0.03442              
  1.6                 0.03355              
  1.5                 0.03252              
  1.4                 0.03142              
  1.3                 0.02969              
  1.2                 0.02719              
  1.1                 0.02523              
  1.                  0.02521              
  0.9                 0.02562              
  0.8                 0.02617              
  0.7                 0.02663              
  0.6                 0.02673              
  0.5                 0.02673              
  0.4                 0.02585              
  0.3                 0.02481              
  0.2                 0.02420              
  0.1                 0.02320              
 -0.00000             0.02230              
 -0.1                 0.02068              
 -0.2                 0.01898              
 -0.3                 0.01898              
 -0.4                 0.01905              
 -0.5                 0.01853              
 -0.6                 0.01715              
 -0.7                 0.01456              
 -0.8                 0.01287              
 -0.9                 0.01368              
 -1.                  0.01529              
 -1.1                 0.01764              
 -1.2                 0.01852              
 -1.3                 0.01615              
 -1.4                 0.01278              
 -1.5                 0.01312              
 -1.6                 0.01573              
 -1.7                 0.01853              
 -1.8                 0.01813              
 -1.9                 0.01463              
 -2.                  0.01213              
 -2.1                 0.01394              
 -2.2                 0.01637              
 -2.3                 0.01692              
 -2.4                 0.01501              
 -2.5                 0.01291              
 -2.6                 0.01378              
 -2.7                 0.01566              
 -2.8                 0.01647              
 -2.9                 0.01618              
 -3.                  0.01485              
 -3.1                 0.01291              
 -3.2                 0.01280              
 -3.3                 0.01116              
 -3.4                 0.00982              
 -3.5                 0.00973              
 -3.6                 0.01029              
 -3.7                 0.01200              
 -3.8                 0.01285              
 -3.9                 0.01205              
 -4.                  0.01089              
 -4.1                 0.01011              
 -4.2                 0.00865              
 -4.3                 0.00681              
 -4.4                 0.00501              
 -4.5                 0.00252              
 -4.6                 0.00111              
 -4.7                 0.00070              
 -4.8                 0.00043              
 -4.9                 0.00196              
 -5.                  0.00368              
 -5.1                 0.00368              
 -5.2                 0.00364              
 -5.3                 0.00364              
 -5.4                 0.00365              
 -5.5                 0.00362              
 -5.6                 0.00357              
 -5.7                 0.00193              
 -5.8                 0.00059              
 -5.9                 0.00049              
 -6.                  0.00105              
 -6.1                 0.00276              
 -6.2                 0.00365              
 -6.3                 0.00366              
 -6.4                 0.00364              
 -6.5                 0.00365              
 -6.6                 0.00360              
 -6.7                 0.00431              
 -6.8                 0.00603              
 -6.9                 0.00667              
 -7.                  0.00630              
 -7.1                 0.00496              
 -7.2                 0.00314              
 -7.3                 0.00281              
 -7.4                 0.00363              
 -7.5                 0.00280              
 -7.6                 0.00253              
 -7.7                 0.00385              
 -7.8                 0.00565              
 -7.9                 0.00667              
 -8.                  0.00665              
 -8.1                 0.00501              
 -8.2                 0.00367              
 -8.3                 0.00361              
 -8.4                 0.00364              
 -8.5                 0.00366              
 -8.6                 0.00369              
 -8.7                 0.00492              
 -8.8                 0.00572              
 -8.9                 0.00495              
 -9                   0.00258              
 -9.1                 0.00199              
 -9.2                 0.00457              
 -9.3                 0.00683              
 -9.4                 0.00866              
 -9.5                 0.00960              
 -9.6                 0.00984              
 -9.7                 0.00979              
 -9.8                 0.00980              
 -9.9                 0.00980              
 -10                  0.00978              
 -10.1                0.01018              
 -10.2                0.01224              
 -10.3                0.01495              
 -10.4                0.01754              
 -10.5                0.01721              
 -10.6                0.01518              
 -10.7                0.01240              
 -10.8                0.00890              
 -10.9                0.00682              
 -11.                 0.00504              
 -11.1                0.00255              
 -11.2                0.00152              
 -11.3                0.00248              
 -11.4                0.00354              
 -11.5                0.00365              
 -11.6                0.00364              
 -11.7                0.00365              
 -11.8                0.00324              
 -11.9                0.00184              
 -12.                 0.00064              
 -12.1                0.00056              
 -12.2                0.00057              
 -12.3                0.00096              
 -12.4                0.00233              
 -12.5                0.00555              
 -12.6                0.00860              
 -12.7                0.01039              
 -12.8                0.01386              
 -12.9                0.01816              
 -13.                 0.02261              
 -13.1                0.02799              
 -13.2                0.03297              
 -13.3                0.04261              
 -13.4                0.05758              
 -13.5                0.07462              
 -13.6                0.09176              
 -13.7                0.11580              
 -13.8                0.14978              
 -13.9                0.18463              
 -14.                 0.20921              
 -14.1                0.25067              
 -14.2                0.29850              
 -14.3                0.34745              
 -14.4                0.38968              
 -14.5                0.43787              
 -14.6                0.49690              
 -14.7                0.54130              
 -14.8                0.57628              
 -14.9                0.61519              
 -15.                 0.65023              
 -15.1                0.66924              
 -15.2                0.68267              
 -15.3                0.69313              
 -15.4                0.69763              
 -15.5                0.69592              
 -15.6                0.69369              
 -15.7                0.68822              
 -15.8                0.67774              
 -15.9                0.66643              
 -16.                 0.65356              
 -16.1                0.62962              
 -16.2                0.60028              
 -16.3                0.57211              
 -16.4                0.54023              
 -16.5                0.49328              
 -16.6                0.44865              
 -16.7                0.40777              
 -16.8                0.36573              
 -16.9                0.32682              
 -17.                 0.29796              
 -17.1                0.27402              
 -17.2                0.25546              
 -17.3                0.24198              
 -17.4                0.23122              
 -17.5                0.22621              
 -17.6                0.22428              
 -17.7                0.22003              
 -17.8                0.21512              
 -17.9                0.20814              
 -18.                 0.19892              
 -18.1                0.19045              
 -18.2                0.18159              
 -18.3                0.16729              
 -18.4                0.15531              
 -18.5                0.14802              
 -18.6                0.13925              
 -18.7                0.13507              
 -18.8                0.14259              
 -18.9                0.15565              
 -19.                 0.17224              
 -19.1                0.20418              
 -19.2                0.24253              
 -19.3                0.27320              
 -19.4                0.31087              
 -19.5                0.36242              
 -19.6                0.40375              
 -19.7                0.43271              
 -19.8                0.46395              
 -19.9                0.48702              
 -20.                 0.48383              
 -20.1                0.46486              
 -20.2                0.44511              
 -20.3                0.41662              
 -20.4                0.38003              
 -20.5                0.34712              
 -20.6                0.32196              
 -20.7                0.29474              
 -20.8                0.27103              
 -20.9                0.25384              
 -21.                 0.24102              
 -21.1                0.23213              
 -21.2                0.22909              
 -21.3                0.23206              
 -21.4                0.23696              
 -21.5                0.24693              
 -21.6                0.26056              
 -21.7                0.27680              
 -21.8                0.29281              
 -21.9                0.31770              
 -22.                 0.34330              
 -22.1                0.36567              
 -22.2                0.38689              
 -22.3                0.41167              
 -22.4                0.43253              
 -22.5                0.44248              
 -22.6                0.44479              
 -22.7                0.43199              
 -22.8                0.40926              
 -22.9                0.38532              
 -23.                 0.35565              
 -23.1                0.31774              
 -23.2                0.28374              
 -23.3                0.24953              
 -23.4                0.21221              
 -23.5                0.17948              
 -23.6                0.15675              
 -23.7                0.12740              
 -23.8                0.10191              
 -23.9                0.08532              
 -24.                 0.07223              
 -24.1                0.06113              
 -24.2                0.05036              
 -24.3                0.04428              
 -24.4                0.03966              
 -24.5                0.03461              
 -24.6                0.03103              
 -24.7                0.02857              
 -24.8                0.02588              
 -24.9                0.02319              
 -25.                 0.02126              
 -25.1                0.01974              
 -25.2                0.01741              
 -25.3                0.01472              
 -25.4                0.01206              
 -25.5                0.01060              
 -25.6                0.00974              
 -25.7                0.01072              
 -25.8                0.01256              
 -25.9                0.01289              
 -26.                 0.01287              
 -26.1                0.01248              
 -26.2                0.01160              
 -26.3                0.00927              
 -26.4                0.00682              
 -26.5                0.00800              
 -26.6                0.00983              
 -26.7                0.01148              
 -26.8                0.01274              
 -26.9                0.01384              
 -27.                 0.01565              
 -27.1                0.01540              
 -27.2                0.01363              
 -27.3                0.01372              
 -27.4                0.01512              
 -27.5                0.01739              
 -27.6                0.01951              
 -27.7                0.01987              
 -27.8                0.01821              
 -27.9                0.01555              
 -28.                 0.01350              
 -28.1                0.01300              
 -28.2                0.01249              
 -28.3                0.01015              
 -28.4                0.00745              
 -28.5                0.00556              
 -28.6                0.00462              
 -28.7                0.00537              
 -28.8                0.00757              
 -28.9                0.00958              
 -29.                 0.01135              
 -29.1                0.01186              
 -29.2                0.01109              
 -29.3                0.00913              
 -29.4                0.00659              
 -29.5                0.00459              
 -29.6                0.00364              
 -29.7                0.00362              
 -29.8                0.00364              
 -29.9                0.00364              
 -30.                 0.00364              
 -30.1                0.00364              
 -30.2                0.00364              
 -30.3                0.00367              
 -30.4                0.00291              
 -30.5                0.00069              
 -30.6               -0.00138              
 -30.7               -0.00244              
 -30.8               -0.00250              
 -30.9               -0.00249              
 -31.                -0.00251              
 -31.1               -0.00246              
 -31.2               -0.00292              
 -31.3               -0.00456              
 -31.4               -0.00557              
 -31.5               -0.00405              
 -31.6               -0.00181              
 -31.7                0.00007              
 -31.8                0.00064              
 -31.9                0.00065              
 -32.                -0.00098              
 -32.1               -0.00150              
 -32.2               -0.00073              
 -32.3                0.00123              
 -32.4                0.00341              
 -32.5                0.00306              
 -32.6                0.00132              
 -32.7               -0.00095              
 -32.8               -0.00212              
 -32.9               -0.00085              
 -33.                 0.00086              
 -33.1                0.00266              
 -33.2                0.00364              
 -33.3                0.00366              
 -33.4                0.00364              
 -33.5                0.00361              
 -33.6                0.00375              
 -33.7                0.00244              
 -33.8               -0.00099              
 -33.9               -0.00468              
 -34.                -0.00749              
 -34.1               -0.00760              
 -34.2               -0.00517              
 -34.3               -0.00144              
 -34.4                0.00211              
 -34.5                0.00462              
 -34.6                0.00620              
 -34.7                0.00568              
 -34.8                0.00402              
 -34.9                0.00360              
 -35.                 0.00364              
 -35.1                0.00368              
 -35.2                0.00291              
 -35.3                0.00111              
 -35.4                0.00044              
 -35.5                0.00058              
 -35.6                0.00056              
 -35.7                0.00057              
 -35.8                0.00084              
 -35.9                0.00277              
 -36.                 0.00452              
 -36.1                0.00262              
 -36.2               -0.00096              
 -36.3               -0.00237              
 -36.4               -0.00181              
 -36.5                0.00003              
 -36.6                0.00066              
 -36.7                0.00063              
 -36.8               -0.00096              
 -36.9               -0.00230              
 -37.                -0.00249              
 -37.1               -0.00273              
 -37.2               -0.00068              
 -37.3                0.00325              
 -37.4                0.00517              
 -37.5                0.00652              
 -37.6                0.00602              
 -37.7                0.00430              
 -37.8                0.00262              
 -37.9                0.00074              
 -38.                 0.00056              
 -38.1                0.00058              
 -38.2                0.00056              
 -38.3                0.00056              
 -38.4                0.00058              
 -38.5                0.00051              
 -38.6                0.00057              
 -38.7               -0.00170              
 -38.8               -0.00472              
 -38.9               -0.00582              
 -39.                -0.00370              
 -39.1               -0.00047              
 -39.2                0.00056              
 -39.3                0.00058              
 -39.4                0.00055              
 -39.5                0.00060              
 -39.6                0.00022              
 -39.7               -0.00202              
 -39.8               -0.00480              
 -39.9               -0.00480              
 -40.                -0.00302              
 -40.1               -0.00026              
 -40.2                0.00076              
 -40.3                0.00054              
 -40.4                0.00056              
 -40.5                0.00056              
 -40.6                0.00056              
 -40.7                0.00056              
 -40.8                0.00056              
 -40.9                0.00056              
 -41.                 0.00056              
 -41.1                0.00052              
 -41.2                0.00127              
 -41.3                0.00305              
 -41.4                0.00383              
 -41.5                0.00305              
 -41.6                0.00137              
 -41.7               -0.00050              
 -41.8               -0.00156              
 -41.9               -0.00069              
 -42.                 0.00041              
 -42.1                0.00059              
 -42.2                0.00056              
 -42.3                0.00092              
 -42.4                0.00184              
 -42.5                0.00322              
 -42.6                0.00374              
 -42.7                0.00364              
 -42.8                0.00364              
 -42.9                0.00404              
 -43.                 0.00419              
 -43.1                0.00392              
 -43.2                0.00274              
 -43.3                0.00074              
 -43.4                0.00056              
 -43.5                0.00059              
 -43.6                0.00025              
 -43.7               -0.00108              
 -43.8               -0.00249              
 -43.9               -0.00137              
 -44.                 0.00128              
 -44.1                0.00281              
 -44.2                0.00361              
 -44.3                0.00365              
 -44.4                0.00364              
##END=
