##TITLE=              29Si MAS NMR spectrum of calcined pure silica Dodecasil-1H
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Groenen et al. Zeolites, 5, 361-363 (1985) Figure 1b
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 14:15:02
##SOURCE REFERENCE=   DOH-29Si-Groenen-1985
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              DOH
##NAMES=              Dodecasil-1H
##SAMPLE DESCRIPTION= Dodecasil-1H, calcined

$$Bibliographic information 
##$AUTHORS=           Groenen, E.J., Alma, N.C., Dorrepaal, J., Hays, G.R., Kortbeek, A.G.
##$TITLE=             Solid-state 29Si n.m.r. spectroscopy of clathrasils; the relationship between the chemical shift and the structure of silicates
##$JOURNAL=           Zeolites
##$VOLUME=            5
##$PAGES=             361-363
##$YEAR=              1985
##$DOI=               10.1016/0144-2449(85)90126-5
##$FIGURE=            Figure 1b

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         4
##$PEAK LABELS=        Si3        Si1/Si2    Si4        Si2/Si1       
##$PEAK TSITES=        T3         T1/T2      T4         T2/T2        
##$PEAK QTYPES=       
##$PEAK POSITIONS=    -120.451   -117.529   -116.575   -115.36    
##$PEAK AREAS=         3.         6.         2.         6.        
##$PEAK WIDTHS=        0.39565    0.36883    0.47407    0.46584   
##$PEAK SHAPES=        1          1          1          1         
##$NUMBERING REF=     Gerke and Gies. Z. Kristallogr. 166, 11-22 (1984)
##$ASSIGN REF=        Groenen et al. Zeolites, 5, 361-363 (1985) Figure 2
##$ASSIGN METHOD=     relative intensities
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -106.06               
##LASTX=              -127.87               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            728
##FIRSTY=             -0.13007              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -106.06             -0.13007              
 -106.09             -0.15530              
 -106.12             -0.17847              
 -106.15             -0.22362              
 -106.18             -0.27199              
 -106.21             -0.31761              
 -106.24             -0.35216              
 -106.27             -0.37285              
 -106.3              -0.38882              
 -106.33             -0.39115              
 -106.36             -0.39253              
 -106.39             -0.37856              
 -106.42             -0.36056              
 -106.45             -0.33674              
 -106.48             -0.31193              
 -106.51             -0.25124              
 -106.54             -0.19043              
 -106.57             -0.16780              
 -106.6              -0.13789              
 -106.63             -0.10886              
 -106.66             -0.08617              
 -106.69             -0.06358              
 -106.72             -0.06633              
 -106.75             -0.07542              
 -106.78             -0.07673              
 -106.81             -0.07858              
 -106.84             -0.09889              
 -106.87             -0.11609              
 -106.9              -0.11599              
 -106.93             -0.11885              
 -106.96             -0.13069              
 -106.99             -0.13740              
 -107.02             -0.13614              
 -107.05             -0.13608              
 -107.08             -0.13665              
 -107.11             -0.12911              
 -107.14             -0.12130              
 -107.17             -0.10437              
 -107.2              -0.08267              
 -107.23             -0.06804              
 -107.26             -0.06002              
 -107.29             -0.05765              
 -107.32             -0.05617              
 -107.35             -0.05646              
 -107.38             -0.05642              
 -107.41             -0.05624              
 -107.44             -0.05701              
 -107.47             -0.05322              
 -107.5              -0.04734              
 -107.53             -0.04633              
 -107.56             -0.04629              
 -107.59             -0.04927              
 -107.62             -0.05512              
 -107.65             -0.05583              
 -107.68             -0.06464              
 -107.71             -0.08363              
 -107.74             -0.11913              
 -107.77             -0.14115              
 -107.8              -0.15466              
 -107.83             -0.17059              
 -107.86             -0.17864              
 -107.89             -0.18679              
 -107.92             -0.18093              
 -107.95             -0.17326              
 -107.98             -0.15969              
 -108.01             -0.14223              
 -108.04             -0.12606              
 -108.07             -0.11675              
 -108.1              -0.11668              
 -108.13             -0.10935              
 -108.16             -0.10540              
 -108.19             -0.11344              
 -108.22             -0.11677              
 -108.25             -0.11574              
 -108.28             -0.11765              
 -108.31             -0.10718              
 -108.34             -0.08828              
 -108.37             -0.07232              
 -108.4              -0.06270              
 -108.43             -0.05041              
 -108.46             -0.03936              
 -108.49             -0.02810              
 -108.52             -0.01451              
 -108.55              0.00002              
 -108.58              0.00232              
 -108.61              0.00261              
 -108.64              0.01511              
 -108.67              0.03541              
 -108.7               0.07286              
 -108.73              0.09759              
 -108.76              0.11672              
 -108.79              0.13448              
 -108.82              0.12555              
 -108.85              0.10855              
 -108.88              0.04277              
 -108.91             -0.01917              
 -108.94             -0.06806              
 -108.97             -0.11386              
 -109.               -0.13969              
 -109.03             -0.15559              
 -109.06             -0.15069              
 -109.09             -0.12785              
 -109.12             -0.09031              
 -109.15             -0.04099              
 -109.18              0.00431              
 -109.21              0.05127              
 -109.24              0.08585              
 -109.27              0.09072              
 -109.3               0.09292              
 -109.33              0.05738              
 -109.36              0.01082              
 -109.39             -0.05463              
 -109.42             -0.10387              
 -109.45             -0.12739              
 -109.48             -0.15183              
 -109.51             -0.15188              
 -109.54             -0.14599              
 -109.57             -0.12551              
 -109.6              -0.10035              
 -109.63             -0.07861              
 -109.66             -0.05205              
 -109.69             -0.03467              
 -109.72             -0.01956              
 -109.75             -0.00780              
 -109.78              0.00182              
 -109.81              0.01213              
 -109.84              0.01756              
 -109.87              0.02288              
 -109.9               0.02378              
 -109.93              0.02374              
 -109.96              0.03704              
 -109.99              0.05572              
 -110.02              0.07602              
 -110.05              0.09222              
 -110.08              0.10769              
 -110.11              0.11833              
 -110.14              0.12610              
 -110.17              0.12976              
 -110.2               0.12732              
 -110.23              0.12440              
 -110.26              0.11912              
 -110.29              0.10587              
 -110.32              0.09219              
 -110.35              0.06590              
 -110.38              0.04619              
 -110.41              0.03242              
 -110.44              0.01586              
 -110.47             -0.00304              
 -110.5              -0.01696              
 -110.53             -0.01622              
 -110.56             -0.01650              
 -110.59             -0.01645              
 -110.62             -0.01638              
 -110.65             -0.01409              
 -110.68             -0.00165              
 -110.71              0.01191              
 -110.74              0.02261              
 -110.77              0.03199              
 -110.8               0.04002              
 -110.83              0.04613              
 -110.86              0.04917              
 -110.89              0.04844              
 -110.92              0.04425              
 -110.95              0.04339              
 -110.98              0.02824              
 -111.01              0.00774              
 -111.04             -0.01236              
 -111.07             -0.02755              
 -111.1              -0.03518              
 -111.13             -0.03115              
 -111.16             -0.02019              
 -111.19             -0.01725              
 -111.22             -0.01413              
 -111.25             -0.00646              
 -111.28              0.00003              
 -111.31              0.00020              
 -111.34             -0.00086              
 -111.37             -0.01281              
 -111.4              -0.02889              
 -111.43             -0.05747              
 -111.46             -0.08452              
 -111.49             -0.09922              
 -111.52             -0.10817              
 -111.55             -0.09043              
 -111.58             -0.06486              
 -111.61             -0.03416              
 -111.64              0.00148              
 -111.67              0.03639              
 -111.7               0.07323              
 -111.73              0.10386              
 -111.76              0.1228               
 -111.79              0.13397              
 -111.82              0.13121              
 -111.85              0.12418              
 -111.88              0.08860              
 -111.91              0.05458              
 -111.94              0.02544              
 -111.97              0.00113              
 -112.               -0.01405              
 -112.03             -0.02670              
 -112.06             -0.02634              
 -112.09             -0.02583              
 -112.12             -0.01595              
 -112.15             -0.00564              
 -112.18             -0.00231              
 -112.21             -0.01247              
 -112.24             -0.02332              
 -112.27             -0.04786              
 -112.3              -0.07737              
 -112.33             -0.1035               
 -112.36             -0.11593              
 -112.39             -0.12324              
 -112.42             -0.13585              
 -112.45             -0.13308              
 -112.48             -0.12691              
 -112.51             -0.12633              
 -112.54             -0.12577              
 -112.57             -0.12921              
 -112.6              -0.13601              
 -112.63             -0.14499              
 -112.66             -0.14285              
 -112.69             -0.12700              
 -112.72             -0.08542              
 -112.75             -0.04932              
 -112.78             -0.00306              
 -112.81              0.03973              
 -112.84              0.09981              
 -112.87              0.16256              
 -112.9               0.22007              
 -112.93              0.25996              
 -112.96              0.26128              
 -112.99              0.26343              
 -113.02              0.24949              
 -113.05              0.23296              
 -113.08              0.21562              
 -113.11              0.20534              
 -113.14              0.21923              
 -113.17              0.2498               
 -113.2               0.29073              
 -113.23              0.34338              
 -113.26              0.38940              
 -113.29              0.43668              
 -113.32              0.47243              
 -113.35              0.49494              
 -113.38              0.51470              
 -113.41              0.52042              
 -113.44              0.52329              
 -113.47              0.52270              
 -113.5               0.52284              
 -113.53              0.52298              
 -113.56              0.52229              
 -113.59              0.52568              
 -113.62              0.53266              
 -113.65              0.54085              
 -113.68              0.54336              
 -113.71              0.54029              
 -113.74              0.53260              
 -113.77              0.52442              
 -113.8               0.51406              
 -113.83              0.50435              
 -113.86              0.49700              
 -113.89              0.49185              
 -113.92              0.53322              
 -113.95              0.58770              
 -113.98              0.63295              
 -114.01              0.66128              
 -114.04              0.66807              
 -114.07              0.67234              
 -114.1               0.66218              
 -114.13              0.61994              
 -114.16              0.56969              
 -114.19              0.50880              
 -114.22              0.45065              
 -114.25              0.41549              
 -114.28              0.39303              
 -114.31              0.39311              
 -114.34              0.39712              
 -114.37              0.43087              
 -114.4               0.47315              
 -114.43              0.50627              
 -114.46              0.52651              
 -114.49              0.54054              
 -114.52              0.55347              
 -114.55              0.55111              
 -114.58              0.54775              
 -114.61              0.54526              
 -114.64              0.55890              
 -114.67              0.57265              
 -114.7               0.64065              
 -114.73              0.72848              
 -114.76              0.81609              
 -114.79              0.89323              
 -114.82              0.97139              
 -114.85              1.02327              
 -114.88              1.08081              
 -114.91              1.13419              
 -114.94              1.29226              
 -114.97              1.49218              
 -115.                1.80659              
 -115.03              2.02546              
 -115.06              2.58022              
 -115.09              3.29821              
 -115.12              3.84653              
 -115.15              4.47086              
 -115.18              5.10768              
 -115.21              5.89009              
 -115.24              6.52854              
 -115.27              7.2249               
 -115.3               7.79                 
 -115.33              8.10284              
 -115.36              8.3918               
 -115.39              8.12784              
 -115.42              7.7343               
 -115.45              6.9909               
 -115.48              6.22607              
 -115.51              5.52917              
 -115.54              4.97088              
 -115.57              4.37412              
 -115.6               3.76708              
 -115.63              3.48735              
 -115.66              3.17073              
 -115.69              2.92975              
 -115.72              2.60701              
 -115.75              2.30557              
 -115.78              2.07332              
 -115.81              1.89515              
 -115.84              1.68329              
 -115.87              1.49466              
 -115.9               1.38344              
 -115.93              1.29816              
 -115.96              1.26994              
 -115.99              1.24945              
 -116.02              1.24162              
 -116.05              1.23365              
 -116.08              1.25075              
 -116.11              1.26855              
 -116.14              1.29365              
 -116.17              1.33174              
 -116.2               1.35848              
 -116.23              1.40741              
 -116.26              1.46161              
 -116.29              1.58036              
 -116.32              1.6838               
 -116.35              1.82469              
 -116.38              2.00391              
 -116.41              2.30468              
 -116.44              2.50357              
 -116.47              2.75885              
 -116.5               3.07743              
 -116.53              3.27491              
 -116.56              3.43396              
 -116.59              3.41233              
 -116.62              3.32437              
 -116.65              3.14576              
 -116.68              2.87471              
 -116.71              2.57671              
 -116.74              2.24575              
 -116.77              2.03157              
 -116.8               1.82634              
 -116.83              1.62443              
 -116.86              1.50829              
 -116.89              1.43782              
 -116.92              1.47195              
 -116.95              1.5164               
 -116.98              1.66676              
 -117.01              1.78861              
 -117.04              1.89836              
 -117.07              2.02103              
 -117.1               2.17025              
 -117.13              2.34109              
 -117.16              2.67129              
 -117.19              3.07846              
 -117.22              3.4832               
 -117.25              4.19995              
 -117.28              4.76539              
 -117.31              5.57761              
 -117.34              6.22456              
 -117.37              6.97491              
 -117.4               7.75737              
 -117.43              8.44692              
 -117.46              9.07616              
 -117.49              9.69072              
 -117.52              10.2853              
 -117.55              10.4889              
 -117.58              10.5665              
 -117.61              9.69031              
 -117.64              8.50764              
 -117.67              7.03878              
 -117.7               5.7707               
 -117.73              4.81326              
 -117.76              3.72828              
 -117.79              3.06891              
 -117.82              2.79172              
 -117.85              2.4848               
 -117.88              2.34218              
 -117.91              2.25461              
 -117.94              2.19389              
 -117.97              2.12996              
 -118.                2.03578              
 -118.03              1.95802              
 -118.06              1.80524              
 -118.09              1.6335               
 -118.12              1.51782              
 -118.15              1.40493              
 -118.18              1.28477              
 -118.21              1.19663              
 -118.24              1.15504              
 -118.27              1.12749              
 -118.3               1.1116               
 -118.33              1.11631              
 -118.36              1.12183              
 -118.39              1.12188              
 -118.42              1.12311              
 -118.45              1.11489              
 -118.48              1.09793              
 -118.51              1.06461              
 -118.54              1.03821              
 -118.57              0.98766              
 -118.6               0.93770              
 -118.63              0.89897              
 -118.66              0.85772              
 -118.69              0.83383              
 -118.72              0.80034              
 -118.75              0.77169              
 -118.78              0.74533              
 -118.81              0.72667              
 -118.84              0.72121              
 -118.87              0.71737              
 -118.9               0.70745              
 -118.93              0.69821              
 -118.96              0.68648              
 -118.99              0.66934              
 -119.02              0.64650              
 -119.05              0.62944              
 -119.08              0.60292              
 -119.11              0.57790              
 -119.14              0.57288              
 -119.17              0.56752              
 -119.2               0.56369              
 -119.23              0.56290              
 -119.26              0.56216              
 -119.29              0.57185              
 -119.32              0.58364              
 -119.35              0.60180              
 -119.38              0.61718              
 -119.41              0.62984              
 -119.44              0.64554              
 -119.47              0.67867              
 -119.5               0.71451              
 -119.53              0.77174              
 -119.56              0.82349              
 -119.59              0.87907              
 -119.62              0.92862              
 -119.65              0.95102              
 -119.68              0.97018              
 -119.71              0.96534              
 -119.74              0.92845              
 -119.77              0.87644              
 -119.8               0.84135              
 -119.83              0.81612              
 -119.86              0.81730              
 -119.89              0.83654              
 -119.92              0.92640              
 -119.95              1.0172               
 -119.98              1.1466               
 -120.01              1.26836              
 -120.04              1.42937              
 -120.07              1.57761              
 -120.1               1.7612               
 -120.13              1.92571              
 -120.16              2.14009              
 -120.19              2.40042              
 -120.22              2.55257              
 -120.25              2.82357              
 -120.28              3.15688              
 -120.31              3.54849              
 -120.34              3.83304              
 -120.37              4.13977              
 -120.4               4.45914              
 -120.43              4.80404              
 -120.46              5.07219              
 -120.49              4.96938              
 -120.52              4.82808              
 -120.55              4.42715              
 -120.58              4.01509              
 -120.61              3.44995              
 -120.64              2.92881              
 -120.67              2.55913              
 -120.7               2.15241              
 -120.73              1.75567              
 -120.76              1.40718              
 -120.79              1.24453              
 -120.82              1.13263              
 -120.85              1.03899              
 -120.88              0.94658              
 -120.91              0.87227              
 -120.94              0.77367              
 -120.97              0.68680              
 -121.                0.60328              
 -121.03              0.52803              
 -121.06              0.45187              
 -121.09              0.37607              
 -121.12              0.33869              
 -121.15              0.31306              
 -121.18              0.31048              
 -121.21              0.30411              
 -121.24              0.30303              
 -121.27              0.30316              
 -121.3               0.30312              
 -121.33              0.30313              
 -121.36              0.30311              
 -121.39              0.30320              
 -121.42              0.30140              
 -121.45              0.29314              
 -121.48              0.2881               
 -121.51              0.27858              
 -121.54              0.26773              
 -121.57              0.23422              
 -121.6               0.19508              
 -121.63              0.13434              
 -121.66              0.07368              
 -121.69              0.03275              
 -121.72             -0.00305              
 -121.75             -0.03290              
 -121.78             -0.02355              
 -121.81              0.01301              
 -121.84              0.07415              
 -121.87              0.12916              
 -121.9               0.20335              
 -121.93              0.27256              
 -121.96              0.32393              
 -121.99              0.35830              
 -122.02              0.35046              
 -122.05              0.33838              
 -122.08              0.29195              
 -122.11              0.23660              
 -122.14              0.16713              
 -122.17              0.11383              
 -122.2               0.08378              
 -122.23              0.06894              
 -122.26              0.08353              
 -122.29              0.14138              
 -122.32              0.19553              
 -122.35              0.23391              
 -122.38              0.27448              
 -122.41              0.30301              
 -122.44              0.31164              
 -122.47              0.26763              
 -122.5               0.22513              
 -122.53              0.17414              
 -122.56              0.12193              
 -122.59              0.06979              
 -122.62              0.03141              
 -122.65              0.01189              
 -122.68             -0.01193              
 -122.71             -0.02537              
 -122.74             -0.04393              
 -122.77             -0.05896              
 -122.8              -0.06950              
 -122.83             -0.07638              
 -122.86             -0.07615              
 -122.89             -0.07703              
 -122.92             -0.07052              
 -122.95             -0.05602              
 -122.98             -0.02640              
 -123.01             -0.00297              
 -123.04              0.01034              
 -123.07              0.02049              
 -123.1               0.03420              
 -123.13              0.05000              
 -123.16              0.05926              
 -123.19              0.06404              
 -123.22              0.06426              
 -123.25              0.05715              
 -123.28              0.04761              
 -123.31              0.03487              
 -123.34              0.02205              
 -123.37              0.00589              
 -123.4              -0.00956              
 -123.43             -0.05885              
 -123.46             -0.11097              
 -123.49             -0.14925              
 -123.52             -0.18171              
 -123.55             -0.21477              
 -123.58             -0.24381              
 -123.61             -0.22039              
 -123.64             -0.18535              
 -123.67             -0.11404              
 -123.7              -0.04452              
 -123.73              0.00293              
 -123.76              0.08650              
 -123.79              0.17141              
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##END=
