##TITLE=              31P MAS NMR spectrum of as-made AlPO-40 (with tetrapropylammonium and tetramethylammonium templates)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Morais et al. Magn. Reson. Chem., 47, 942-947 (2009) Figure 1a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/16 11:33:25
##SOURCE REFERENCE=   AFR-31P-Morais-2009-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              AFR
##NAMES=              AlPO-40
##SAMPLE DESCRIPTION= AlPO-40, as-made

$$Bibliographic information 
##$AUTHORS=           Morais, C.M., Montouillout, V., Deschamps, M., Iuga, D., Fayon, F., Paz, F.A.A., Rocha, J., Fernandez, C., Massiot, D.
##$TITLE=             1D to 3D NMR study of microporous alumino-phosphate AlPO4-40
##$JOURNAL=           Magnetic Resonance in Chemistry
##$VOLUME=            47
##$PAGES=             942-947
##$YEAR=              2009
##$DOI=               10.1002/mrc.2492
##$FIGURE=            Figure 1a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         32
##$PEAK LABELS=        A          B          D          C          E          F          G          H          I          J          K          L          M          N          O          P          Q          R          S          T          U          V          W          X          Y          Z          AA         AC         AB         AD         AE         AF        
##$PEAK TSITES=       
##$PEAK POSITIONS=    -30.2319   -29.7486   -28.9764   -28.8279   -28.7103   -28.6103   -28.5103   -28.4892   -27.315    -26.8591   -26.7947   -26.5368   -25.323    -25.158    -25.075    -24.8923   -22.8891   -22.6729   -21.5773   -21.2899   -21.0074   -20.4996   -19.0266   -18.4367   -18.0865   -17.3502   -16.4541   -15.6637   -15.5637   -14.7417   -14.5852   -13.9793   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318    0.67318   
##$PEAK SHAPES=        0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861    0.87861   
##$NUMBERING REF=     Ramaswamy et al. Microporous Mesoporous Mater., 31, 1-8 (1999)
##$ASSIGN REF=        
##$ASSIGN METHOD=     
##$COMMENT=           There are 4x as many peaks as there are in the crystal structure

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 303.6
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     14000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -9.96                 
##LASTX=              -34.92                
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            417
##FIRSTY=              0.07894              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -9.96                0.07894              
 -10.02               0.07894              
 -10.08               0.07894              
 -10.14               0.07894              
 -10.2                0.07894              
 -10.26               0.07895              
 -10.32               0.07891              
 -10.38               0.07908              
 -10.44               0.07843              
 -10.5                0.08138              
 -10.56               0.09188              
 -10.62               0.09713              
 -10.68               0.09626              
 -10.74               0.09649              
 -10.8                0.09643              
 -10.86               0.09645              
 -10.92               0.09644              
 -10.98               0.09644              
 -11.04               0.09644              
 -11.1                0.09644              
 -11.16               0.09645              
 -11.22               0.09640              
 -11.28               0.09662              
 -11.34               0.09579              
 -11.4                0.10013              
 -11.46               0.11072              
 -11.52               0.11455              
 -11.58               0.11379              
 -11.64               0.11396              
 -11.7                0.11400              
 -11.76               0.11368              
 -11.82               0.11582              
 -11.88               0.12333              
 -11.94               0.13199              
 -12.                 0.13641              
 -12.06               0.13894              
 -12.12               0.14237              
 -12.18               0.14303              
 -12.24               0.14521              
 -12.3                0.15333              
 -12.36               0.15989              
 -12.42               0.16050              
 -12.48               0.16298              
 -12.54               0.17091              
 -12.6                0.18                 
 -12.66               0.18856              
 -12.72               0.19874              
 -12.78               0.20829              
 -12.84               0.22467              
 -12.9                0.23932              
 -12.96               0.25276              
 -13.02               0.27197              
 -13.08               0.28356              
 -13.14               0.30160              
 -13.2                0.33846              
 -13.26               0.37319              
 -13.32               0.40444              
 -13.38               0.44907              
 -13.44               0.5017               
 -13.5                0.56803              
 -13.56               0.65551              
 -13.62               0.76021              
 -13.68               0.87248              
 -13.74               1.02197              
 -13.8                1.16367              
 -13.86               1.33029              
 -13.92               1.47127              
 -13.98               1.56387              
 -14.04               1.63142              
 -14.1                1.64913              
 -14.16               1.63736              
 -14.22               1.62423              
 -14.28               1.63218              
 -14.34               1.69974              
 -14.4                1.82307              
 -14.46               1.96476              
 -14.52               2.15671              
 -14.58               2.3069               
 -14.64               2.38821              
 -14.7                2.38208              
 -14.76               2.28771              
 -14.82               2.16103              
 -14.88               1.9769               
 -14.94               1.77979              
 -15.                 1.64374              
 -15.06               1.54883              
 -15.12               1.52001              
 -15.18               1.53449              
 -15.24               1.59077              
 -15.3                1.71826              
 -15.36               1.87844              
 -15.42               2.0536               
 -15.48               2.23899              
 -15.54               2.38992              
 -15.6                2.50207              
 -15.66               2.43757              
 -15.72               2.27636              
 -15.78               2.10208              
 -15.84               1.87812              
 -15.9                1.69853              
 -15.96               1.5459               
 -16.02               1.4478               
 -16.08               1.39471              
 -16.14               1.37534              
 -16.2                1.41723              
 -16.26               1.48142              
 -16.32               1.53881              
 -16.38               1.58178              
 -16.44               1.59223              
 -16.5                1.55976              
 -16.56               1.47869              
 -16.62               1.381                
 -16.68               1.25919              
 -16.74               1.17071              
 -16.8                1.11225              
 -16.86               1.06163              
 -16.92               1.05034              
 -16.98               1.0693               
 -17.04               1.12999              
 -17.1                1.21781              
 -17.16               1.32646              
 -17.22               1.44712              
 -17.28               1.53823              
 -17.34               1.61136              
 -17.4                1.62304              
 -17.46               1.56365              
 -17.52               1.50421              
 -17.58               1.4328               
 -17.64               1.36275              
 -17.7                1.32682              
 -17.76               1.33027              
 -17.82               1.39127              
 -17.88               1.48261              
 -17.94               1.5882               
 -18                  1.71399              
 -18.06               1.82333              
 -18.12               1.93192              
 -18.18               2.00034              
 -18.24               2.02906              
 -18.3                2.04368              
 -18.36               2.01789              
 -18.42               1.96182              
 -18.48               1.88098              
 -18.54               1.80324              
 -18.6                1.70722              
 -18.66               1.59688              
 -18.72               1.55839              
 -18.78               1.55132              
 -18.84               1.5694               
 -18.9                1.60072              
 -18.96               1.62246              
 -19.02               1.60568              
 -19.08               1.54887              
 -19.14               1.43175              
 -19.2                1.30165              
 -19.26               1.15563              
 -19.32               1.01873              
 -19.38               0.91145              
 -19.44               0.79674              
 -19.5                0.73377              
 -19.56               0.68437              
 -19.62               0.63522              
 -19.68               0.61062              
 -19.74               0.60439              
 -19.8                0.59649              
 -19.86               0.60143              
 -19.92               0.62051              
 -19.98               0.65771              
 -20.04               0.70701              
 -20.1                0.7785               
 -20.16               0.87605              
 -20.22               0.98965              
 -20.28               1.13745              
 -20.34               1.27213              
 -20.4                1.42161              
 -20.46               1.54545              
 -20.52               1.62093              
 -20.58               1.65902              
 -20.64               1.67289              
 -20.7                1.71378              
 -20.76               1.79529              
 -20.82               1.90289              
 -20.88               2.0341               
 -20.94               2.20087              
 -21.                 2.31411              
 -21.06               2.39891              
 -21.12               2.41961              
 -21.18               2.38978              
 -21.24               2.3775               
 -21.3                2.37135              
 -21.36               2.3924               
 -21.42               2.38222              
 -21.48               2.34409              
 -21.54               2.22558              
 -21.6                2.05987              
 -21.66               1.86651              
 -21.72               1.60967              
 -21.78               1.43719              
 -21.84               1.29688              
 -21.9                1.16964              
 -21.96               1.07538              
 -22.02               1.01131              
 -22.08               0.98150              
 -22.14               0.96234              
 -22.2                1.0014               
 -22.26               1.07024              
 -22.32               1.16046              
 -22.38               1.28275              
 -22.44               1.37388              
 -22.5                1.48408              
 -22.56               1.62339              
 -22.62               1.79011              
 -22.68               1.96211              
 -22.74               2.0825               
 -22.8                2.12375              
 -22.86               2.0368               
 -22.92               1.88028              
 -22.98               1.69301              
 -23.04               1.48547              
 -23.1                1.27639              
 -23.16               1.12053              
 -23.22               0.96071              
 -23.28               0.8417               
 -23.34               0.76373              
 -23.4                0.69491              
 -23.46               0.65290              
 -23.52               0.60956              
 -23.58               0.58103              
 -23.64               0.56104              
 -23.7                0.55329              
 -23.76               0.55098              
 -23.82               0.55215              
 -23.88               0.55342              
 -23.94               0.57073              
 -24.                 0.60592              
 -24.06               0.63246              
 -24.12               0.66141              
 -24.18               0.71245              
 -24.24               0.78283              
 -24.3                0.83872              
 -24.36               0.92754              
 -24.42               1.04675              
 -24.48               1.18736              
 -24.54               1.33872              
 -24.6                1.53025              
 -24.66               1.81662              
 -24.72               2.10753              
 -24.78               2.44153              
 -24.84               2.77473              
 -24.9                3.07451              
 -24.96               3.3474               
 -25.02               3.55774              
 -25.08               3.69724              
 -25.14               3.6862               
 -25.2                3.60158              
 -25.26               3.44139              
 -25.32               3.17802              
 -25.38               2.88201              
 -25.44               2.55264              
 -25.5                2.26611              
 -25.56               1.99474              
 -25.62               1.76745              
 -25.68               1.56748              
 -25.74               1.41757              
 -25.8                1.31878              
 -25.86               1.23873              
 -25.92               1.19976              
 -25.98               1.18774              
 -26.04               1.18104              
 -26.1                1.22453              
 -26.16               1.30243              
 -26.22               1.39144              
 -26.28               1.53567              
 -26.34               1.72268              
 -26.4                1.93799              
 -26.46               2.1945               
 -26.52               2.45947              
 -26.58               2.72899              
 -26.64               2.94973              
 -26.7                3.12715              
 -26.76               3.18097              
 -26.82               3.12031              
 -26.88               3.02425              
 -26.94               2.85975              
 -27.                 2.72571              
 -27.06               2.61684              
 -27.12               2.4984               
 -27.18               2.3861               
 -27.24               2.26415              
 -27.3                2.11055              
 -27.36               1.93999              
 -27.42               1.78847              
 -27.48               1.63241              
 -27.54               1.5266               
 -27.6                1.44724              
 -27.66               1.3845               
 -27.72               1.36092              
 -27.78               1.3739               
 -27.84               1.42515              
 -27.9                1.48858              
 -27.96               1.60559              
 -28.02               1.72482              
 -28.08               1.93511              
 -28.14               2.19871              
 -28.2                2.4923               
 -28.26               2.90751              
 -28.32               3.37262              
 -28.38               3.85274              
 -28.44               4.29482              
 -28.5                4.76267              
 -28.56               5.11296              
 -28.62               5.24227              
 -28.68               5.2486               
 -28.74               5.09048              
 -28.8                4.87891              
 -28.86               4.59124              
 -28.92               4.2011               
 -28.98               3.8801               
 -29.04               3.49873              
 -29.1                3.12539              
 -29.16               2.74861              
 -29.22               2.42786              
 -29.28               2.17432              
 -29.34               1.93822              
 -29.4                1.78518              
 -29.46               1.68561              
 -29.52               1.64142              
 -29.58               1.64557              
 -29.64               1.67161              
 -29.7                1.70601              
 -29.76               1.74347              
 -29.82               1.75874              
 -29.88               1.74454              
 -29.94               1.72723              
 -30.                 1.70147              
 -30.06               1.68737              
 -30.12               1.6691               
 -30.18               1.62419              
 -30.24               1.53409              
 -30.3                1.42096              
 -30.36               1.28479              
 -30.42               1.10177              
 -30.48               0.96481              
 -30.54               0.83491              
 -30.6                0.71429              
 -30.66               0.61802              
 -30.72               0.53558              
 -30.78               0.47438              
 -30.84               0.41518              
 -30.9                0.36755              
 -30.96               0.33350              
 -31.02               0.30256              
 -31.08               0.27453              
 -31.14               0.25293              
 -31.2                0.22436              
 -31.26               0.20814              
 -31.32               0.19936              
 -31.38               0.18539              
 -31.44               0.16888              
 -31.5                0.15744              
 -31.56               0.14921              
 -31.62               0.14017              
 -31.68               0.13158              
 -31.74               0.12199              
 -31.8                0.11785              
 -31.86               0.11146              
 -31.92               0.09961              
 -31.98               0.09132              
 -32.04               0.09106              
 -32.1                0.08480              
 -32.16               0.07460              
 -32.22               0.07261              
 -32.28               0.07380              
 -32.34               0.06685              
 -32.4                0.05796              
 -32.46               0.05517              
 -32.52               0.05500              
 -32.58               0.05094              
 -32.64               0.04538              
 -32.7                0.04423              
 -32.76               0.04191              
 -32.82               0.03144              
 -32.88               0.02576              
 -32.94               0.02663              
 -33.                 0.02640              
 -33.06               0.02646              
 -33.12               0.02644              
 -33.18               0.02646              
 -33.24               0.02639              
 -33.3                0.02666              
 -33.36               0.02531              
 -33.42               0.01826              
 -33.48               0.01060              
 -33.54               0.00871              
 -33.6                0.00902              
 -33.66               0.00893              
 -33.72               0.00895              
 -33.78               0.00895              
 -33.84               0.00894              
 -33.9                0.00900              
 -33.96               0.00877              
 -34.02               0.00962              
 -34.08               0.00505              
 -34.14              -0.00552              
 -34.2               -0.00913              
 -34.26              -0.00838              
 -34.32              -0.00858              
 -34.38              -0.00853              
 -34.44              -0.00854              
 -34.5               -0.00854              
 -34.56              -0.00854              
 -34.62              -0.00854              
 -34.68              -0.00852              
 -34.74              -0.00860              
 -34.8               -0.00829              
 -34.86              -0.01030              
 -34.92              -0.01409              
##END=
